The Journal of Chemical Physics · 1951 · 474 citations · 3 references
Natural SciencesChemistryPhysicsMolecular PhysicsPhysical ChemistryQuantum ChemistryDielectric PropertiesDielectric ResponseDielectricsRefractive IndexSolvation TheoryDielectric ConstantDielectric FunctionDielectric Properties Of FluidsDielectric Properties Of SolutionsField-dependent Dielectric ResponseLangevin EquationsPolar DielectricsSaturation
The study extends Onsager and Kirkwood theories to derive expressions for the dielectric constant at high electric field strengths. The authors applied the extended theories to water, deriving simple formulas that incorporate the Langevin function and specific numerical factors for the Onsager and Kirkwood methods. The resulting formula predicts a reduction of the dielectric constant due to saturation, becoming significant for fields exceeding 10^6 V cm⁻¹.
The Onsager and Kirkwood theories of polar dielectrics are extended to give expressions for the dielectric constant at high field strengths. The theory is applied in detail to water and simple formulas for the dielectric constant in terms of well-known quantities are obtained. The results of the calculation are embodied in the formula ε=n2+απN0(n2+2)μνEL(βμν(n2+2)EkT),where n is the optical refractive index, N0 the number of molecules per unit volume, μv the dipole moment of the water molecule, E is the field strength, and T the absolute temperature. L(x) is the usual Langevin function, and α and β are numerical factors which have the following values (a) Onsager method α=4/3, β=1/2.(b) Kirkwood method α=28/3√73, β=√73/6.From these formulas it is shown that the reduction of the dielectric constant due to the saturation effect is of importance for fields greater than 106 volts per cm.
3
Electric Moments of Molecules in Liquids
Lars Onsager · Journal of the American Chemical Society · 1936 · 5.3K citations
The Dielectric Polarization of Polar Liquids
John G. Kirkwood · The Journal of Chemical Physics · 1939 · 1.9K citations
Natural Sciences, Chemistry, Physics +17
General theory of the static dielectric constant
H. Fröhlich · Transactions of the Faraday Society · 1948 · 138 citations
Natural Sciences, Chemistry, Physics +12