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Improved regioselectivity in the hydroformylation reaction catalysed by zeolite-encapsulated rhodium(I) species
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Citations
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References
1996
Year
Chemical EngineeringEngineeringBiochemistryHydroformylation ReactionNatural SciencesHomogeneous AnaloguesZeolite-encapsulated RhodiumOrganic ChemistryHex-1-ene RelativePr3= Pet3CatalysisOrganometallic CatalysisChemistryHomogeneous CatalysisMolecular CatalysisZeoliteEnantioselective SynthesisCatalytic Synthesis
Although zeolite-encapsulated [Rh(CO)x(PR3)y](PR3= PEt3, PEt2Ph, PPrn3 or PPh3) give similar chemoselectivities in the hydrocarbonylation of hex-1-ene relative to their homogeneous analogues, the linear : branched ratio can be increased by as much as 10 times.
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