Crystal Growth & Design · 2006 · 79 citations · 45 references
Natural SciencesChemistryMaterials ScienceCrystal StructureSolid-state ChemistrySupramolecular ChemistryCoordination ChemistryCoordination PolymersCrystal ChemistryPolymer StructureSupramolecular MaterialsSupramolecular PolymersLuminescent Metal-organic FrameworksLuminescent PolymersMetal-organic Supramolecular AssembliesSupramolecular Coordination ChemistrySupramolecular Coordination ComplexesSupramolecular InteractionsSupramolecular NetworksTriple Helix Structure
Two 1D polymeric chain structures, namely, {[Ag(3-impmd)]·(SbF 6 )·CH 2 Cl 2 } ∞ ( 1 ) and {[Ag(3-impmd)]·(NO 3 )·MeOH} ∞ ( 2 ), were assembled from the flexible organic spacer N,N ‘-bis(3-imidazol-1-yl-propyl)-pyromellitic diimide (3-impmd) with AgSbF 6 and AgNO 3, respectively. Complex 1 crystallizes with the 1D chains displaying cross-like arrangement, while Complex 2 presents a triple-stranded helical structure, which is dictated by the anions and further assembled into 3D architectures via various weak supramolecular interactions. The luminescent properties of both complexes were investigated in solution and solid state.
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Reticular synthesis and the design of new materials
Omar M. Yaghi, M. O’Keeffe, N.W. Ockwig et al. · Nature · 2003 · 9K citations
Natural Sciences, Materials Engineering, Materials Science +9