Concepedia

Surfactant-free synthesis of amphiphilic diblock copolymer nanoparticles via nitroxide-mediated emulsion polymerization

Guillaume Delaittre, Julien Nicolas, Catherine Lefay, Maud Save, Bernadette Charleux

Chemical Communications · 2004 · 151 citations · 10 references

DOI

Concepts

Abstract

Amphiphilic hairy nanoparticles are prepared in a one step, batch, heterogeneous polymerization of styrene or n-butyl acrylate, using a water-soluble poly(sodium acrylate) alkoxyamine macroinitiator based on the SG1 nitroxide.

References

10

Multiple Morphologies and Characteristics of “Crew-Cut” Micelle-like Aggregates of Polystyrene-<i>b</i>-poly(acrylic acid) Diblock Copolymers in Aqueous Solutions

Lifeng Zhang, Adi Eisenberg · Journal of the American Chemical Society · 1996 · 1.3K citations

, , +16

Controlled/living radical polymerization in aqueous media: homogeneous and heterogeneous systems

Jian Qiu, Bernadette Charleux, Krzysztof Matyjaszewski · Progress in Polymer Science · 2001 · 585 citations

, , +16

Effective ab Initio Emulsion Polymerization under RAFT Control

Christopher J. Ferguson, Robert Hughes, Binh T. T. Pham et al. · Macromolecules · 2002 · 423 citations

, , +13

First Nitroxide-Mediated Controlled Free-Radical Polymerization of Acrylic Acid

Laurence Couvreur, Catherine Lefay, Joël Belleney et al. · Macromolecules · 2003 · 295 citations

, , +7

Living/controlled radical polymerizations in dispersed phase systems

Michael F. Cunningham · Progress in Polymer Science · 2002 · 291 citations

, , +12