A novel method of highly enantioselective synthesis of γ-hydroxy-β-keto phosphonates via allene oxides

The first practical method for asymmetric epoxidation

Tsutomu Katsuki, K. Barry Sharpless · Journal of the American Chemical Society · 1980 · 2.6K citations

Natural Sciences, Chemistry, Analytical Chemistry +5

Catalytic asymmetric epoxidation and kinetic resolution: modified procedures including in situ derivatization

Yun Gao, Janice M. Klunder, Robert M. Hanson et al. · Journal of the American Chemical Society · 1987 · 1.9K citations

Natural Sciences, Biochemistry, Chemistry +15

Direct synthesis of Z-unsaturated esters. A useful modification of the horner-emmons olefination.

W. Clark Still, Cesare Gennari · Tetrahedron Letters · 1983 · 1K citations

Natural Sciences, Chemistry, Organic Chemistry +2

Horner-wadsworth-emmons reaction: Use of lithium chloride and an amine for base-sensitive compounds

Mary A. Blanchette, William Choy, Jeffery T. Davis et al. · Tetrahedron Letters · 1984 · 910 citations

Natural Sciences, Chemistry, Inorganic Chemistry +1

Cp2TiCl2-Catalyzed Grignard exchange reactions with acetylenes. A convenient method for preparation of E-alkenyl Grignard reagents

Fumie Sato, Hiroaki Ishikawa, Masao Satô · Tetrahedron Letters · 1981 · 105 citations

Natural Sciences, Chemical Engineering, Chemistry +9