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Novel Clathrate Compound of Cadmium Cyanide Host with an Adamantane-like Cavity. Cadmium Cyanide-Carbon Tetrachloride(1/1)
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1988
Year
Materials ScienceInorganic ChemistryChemical EngineeringCadmium CyanideTitle Clathrate CompoundEngineeringCadmium Cyanide HostAdamantane-like CavityOrganic ChemistryTetrahedral ConfigurationCoordination PolymerChemistryNovel Clathrate CompoundOrganometallic PolymerCrystallographyInorganic SynthesisInorganic Compound
Abstract Carbon tetrachloride molecule is accommodated in the cavity formed in the three-dimensional framework of cadmium cyanide to give the title clathrate compound. The cavity has a shape of adamantane-like cage edged with –Cd–CN–Cd– linkage where the Cd atom takes a tetrahedral configuration.