Novel Clathrate Compound of Cadmium Cyanide Host with an Adamantane-like Cavity. Cadmium Cyanide-Carbon Tetrachloride(1/1)

Takafumi Kitazawa, S. Nishikiori, Reiko Kuroda, Toschitake Iwamoto

Chemistry Letters · 1988 · 64 citations · 0 references

Concepts

Abstract

Abstract Carbon tetrachloride molecule is accommodated in the cavity formed in the three-dimensional framework of cadmium cyanide to give the title clathrate compound. The cavity has a shape of adamantane-like cage edged with –Cd–CN–Cd– linkage where the Cd atom takes a tetrahedral configuration.