Chemistry Letters · 1988 · 64 citations · 0 references
Natural SciencesChemistryCrystal StructureInorganic ChemistryOrganic ChemistryCluster ChemistryCluster CompoundsCoordination ChemistryMetal-ligand BondingTransition Metal ChemistryTransition Metal ComplexesClathratesTetrahedral Coordination
Abstract Carbon tetrachloride molecule is accommodated in the cavity formed in the three-dimensional framework of cadmium cyanide to give the title clathrate compound. The cavity has a shape of adamantane-like cage edged with –Cd–CN–Cd– linkage where the Cd atom takes a tetrahedral configuration.