A monocapped octahedral form of Rh7[metal atom] cluster in the tetramethylammonium salt of hexadecacarbonylheptarhodate trianion

Abstract

Hexadecacarbonylheptarhodate trianion, [Rh7(CO)16]3–, has been found to be a monocapped octahedron of metal atoms with seven terminal, six double-bridging, and three face-bridging carbonyl groups.