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Photosensitive Cholesteric Copolymers with Spiropyran-Containing Side Groups: Novel Materials for Optical Data Recording
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1999
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Optical MaterialsVisible LightEngineeringResponsive PolymersSpiropyran-containing Side GroupsChemistryChemical ReversibilityOptical PropertiesPhotopolymer NetworkOptical SystemsPolymer ChemistryBiophysicsOptical Data RecordingPhotochemistrySupramolecular PhotochemistryPhotochromismInformation OpticPhotosensitive Cholesteric CopolymersPolymer ScienceMolecular SwitchHelical Supramolecular Architecture
The thermal and chemical reversibility of the photochromic process displayed by spiropyran (see Figure) is combined with the helical supramolecular architecture of a cholesteric polymer to produce a copolymer that can be used for reversible data recording on colored backgrounds. The cholesteric structure is able to reflect a broad spectrum of visible light, which should allow the realization of the special filters and reflectors required for complex multicolor optical display devices.