Reversible DI-π-methane rearrangements of bicyclic organosilicon compounds

Reactions of 7,8-disilabicyclo[2.2.2]octa-2,5-dienes. Evidence for the transient existence of a disilene

David N. Roark, G. J. D. Peddle · Journal of the American Chemical Society · 1972 · 115 citations

Natural Sciences, Chemistry, Organic Chemistry +6

An alternative mechanism for the formation of 1,4-disilacyclohexa-2,5-dienes from acetylenes and silylenes

Thomas J. Barton, John A. Kilgour · Journal of the American Chemical Society · 1976 · 69 citations

Natural Sciences, Chemistry, Analytical Chemistry +8

Chemistry of organosilicon compounds. 109. trans- and cis-1,2-Dimethyl-1,2-diphenyldisilene. Is Silicon:silicon a true double bond?

Hideki Sakurai, Yasuhiro Nakadaira, Toshiaki Kobayashi · Journal of the American Chemical Society · 1979 · 53 citations

Natural Sciences, Chemistry, Inorganic Chemistry +9

2,3-Bis(trifluoromethyl)-7,7-dimethyl-7-silabicyclo[2.2.2] octa-2,5-diene. A silaalkene generator.

Thomas J. Barton, Eugene Arden Kline · Journal of Organometallic Chemistry · 1972 · 41 citations

Natural Sciences, Chemistry, Organic Chemistry +8

Thermal interconversion of naphthobarrelene- and naphthosemibullvalene-like compounds. Ground-state counterpart of a di-.pi.-methane photorearrangement

Martin Demuth, Ulrich Bürger, H.W. Mueller et al. · Journal of the American Chemical Society · 1979 · 14 citations

Natural Sciences, Chemistry, Inorganic Chemistry +7