Physical review. B, Condensed matter · 2001 · 17 citations · 22 references
Natural SciencesMaterials SciencePhysicsCondensed Matter PhysicsSurface ChemistrySurface ScienceSemiconductor SurfacesSurface Chemistry Of SolidsSurface CrystallographySurface EnergeticsSurface PhysicsSurface SpectroscopyMetallizationPeriodicitySilicon ChemistrySilicon Surface ScienceSurface PeriodicitySurface StabilitySurface States
We provide evidence for the temperature-induced metallization (TIM) of Si(100) surface. A TIM takes place at about 600 K without any change in surface periodicity. Contrary to previous suggestions, photoemission spectroscopy (PES) reveals that the TIM is not related to the (instantaneous) symmetrization of asymmetric dimers. We suggest that Si adatoms produced at elevated temperatures play a role of donor, giving rise to the TIM.
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