Concepedia

Observations on the reaction of O-acylthiohydroxamates with thionitrite esters: a novel free radical chain reaction for decarboxylative amination

Pierre Marie Girard, N Guillot, William B. Motherwell, Pierre Potìer

Journal of the Chemical Society Chemical Communications · 1995 · 19 citations · 12 references

DOI

Concepts

Abstract

Treatment of primary and secondary O-acyl derivatives of N-hydroxy-2-thiopyridone with thionitrite esters gives trans nitroso dimers in a free radical chain reaction.

References

12

The invention of new radical chain reactions. Part VIII. Radical chemistry of thiohydroxamic esters; A new method for the generation of carbon radicals from carboxylic acids

Derek H. R. Barton, David Crich, William B. Motherwell · Tetrahedron · 1985 · 528 citations

, , +11

A New Photochemical Reaction<sup>1</sup>

D. H. R. BARTON, J. M. Beaton, L. E. Geller et al. · Journal of the American Chemical Society · 1961 · 431 citations

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Kinetics of the reversible .beta.-scission of the cyclopentyloxy radical

A. L. J. BECKWITH, Benjamin P. Hay · Journal of the American Chemical Society · 1989 · 147 citations

, , +4

Generation of alkoxy radicals from N-alkoxypyridinethiones

A. L. J. BECKWITH, Benjamin P. Hay · Journal of the American Chemical Society · 1988 · 123 citations

, , +6

Syntheses and Reactions of Glycosylcobaloximes

A. Ghosez, Thomas Göbel, Bernd Giese · Chemische Berichte · 1988 · 78 citations

, , +7