Concepedia

The first side-on bound metal complex of diazene, HNNH

Leslie D. Field, Hsiu L. Li, Scott J. Dalgarno, Peter Turner

Chemical Communications · 2008 · 73 citations · 40 references

DOI

Concepts

Abstract

The side-on bound metal complex of diazene cis-[Fe(NH[double bond]NH)(dmpe)(2)] was synthesised by reaction of [Fe(dmpe)(2)Cl(2)] with hydrazine in the presence of potassium graphite and characterised by (15)N NMR spectroscopy and X-ray crystallography.

References

40

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Nitrogenase Model Compounds: [μ‐N<sub>2</sub>H<sub>2</sub>{Fe(“N<sub>H</sub>S<sub>4</sub>”)}<sub>2</sub>], the Prototype for the Coordination of Diazene to Iron Sulfur Centers and Its Stabilization through Strong NH S Hydrogen Bonds

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, , +15