Concepedia

Pd(OAc)<sub>2</sub> Catalyzed Olefination of Highly Electron-Deficient Perfluoroarenes

Xingang Zhang, Shilu Fan, Chun‐Yang He, Xiaolong Wan, Qiao‐Qiao Min, Jie Yang, Zhong‐Xing Jiang

Journal of the American Chemical Society · 2010 · 214 citations · 28 references

DOI

Concepts

Abstract

An efficient, Pd(OAc)(2) catalyzed method for direct olefination of highly electron-deficient perfluoroarenes was developed. The reaction scope includes a series of activated and nonactivated alkenes in moderate to high yields with moderate to high regio- and stereoselectivities.

References

28

Palladium-Catalyzed Benzene Arylation:  Incorporation of Catalytic Pivalic Acid as a Proton Shuttle and a Key Element in Catalyst Design

Marc Lafrance, Keith Fagnou · Journal of the American Chemical Society · 2006 · 994 citations

, , +17

Catalytic Intermolecular Direct Arylation of Perfluorobenzenes

Marc Lafrance, Christopher N. Rowley, Tom K. Woo et al. · Journal of the American Chemical Society · 2006 · 843 citations

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Efficient Activation of Aromatic C-H Bonds for Addition to C-C Multiple Bonds

Chengguo Jia, Dongguo Piao, Juzo Oyamada et al. · Science · 2000 · 819 citations

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Palladium-Catalyzed C−H Functionalization of Pyridine <i>N</i>-Oxides: Highly Selective Alkenylation and Direct Arylation with Unactivated Arenes

Seung Hwan Cho, Seung Jun Hwang, Sukbok Chang · Journal of the American Chemical Society · 2008 · 671 citations

, , +16

Palladium‐Catalyzed Intermolecular Alkenylation of Indoles by Solvent‐Controlled Regioselective CH Functionalization

Neil P. Grimster, Carolyn Gauntlett, Christopher R. A. Godfrey et al. · Angewandte Chemie International Edition · 2005 · 635 citations

, , +17