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Pentaco-ordinate silicon derivatives:<sup>1</sup>H n.m.r. evidence
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1980
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Inorganic ChemistryPentaco-ordinate Silicon DerivativesEngineeringNatural SciencesSi–x BondChemical BondApplied PhysicsMolecular BiologyPhysical ChemistryIntramolecular Si–n Co-ordinationChemistryMolecular ChemistrySilicon On InsulatorSpectra-structure Correlation
The 1H n.m.r. spectra of o-(Me2NCH2)C6H4SiX2R and o-(Me2NCH2)C6H4SiXR1R2 indicate that the intramolecular Si–N co-ordination is controlled by the ability of the Si–X bond to be stretched and substituted with inversion of configuration.