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Seven-coordinate dioxygen complexes from dioxygen addition to five-coordinate σ-phenyl, isocyanide-containing derivatives of ruthenium(II) and osmium(II). Crystal structures of OS(η2-O2)(η2-CPh = Np-chlorophenyl)Cl(PPh3)2 and Os(η2-SO4)(η2-CPh = Np-chlorophenyl)Cl(PPh3)2

Inorganic ChemistryChemical EngineeringSeven-coordinate Dioxygen ComplexesIsocyanide-containing DerivativesDioxygen AdditionEngineeringCoordination ComplexMolecular ComplexChemistryInorganic SynthesisInorganic Compound