New Amines for CO₂ Capture. III. Effect of Alkyl Chain Length between Amine Functions on Polyamines Degradation

Abstract

This study examines degradation of five tertiary polyamines (di- and triamines) in the presence of CO2 or O2. They were chosen to identify the impact of alkyl chain length between amine functions. Degradation of aqueous amine solutions was evaluated at 140 °C under CO2 or air pressure (2 MPa) in stainless steel batch reactors for 15 days. At the end of the run, most degradation products were identified by gas chromatography (GC)/mass spectrometry; amounts of remaining amine and its degradation products were determined with a quantitative GC method. The main degradation mechanisms are proposed, and some structure−properties relationships are established.