Publication | Closed Access
Influence of the Bulk and Donor-Acceptor Properties of Solvent on Ligand Field Spectra
15
Citations
9
References
1989
Year
Few AlcoholsChemical EngineeringDielectric ConstantLiterature Donor NumbersEngineeringMolecular SpectroscopyDonor-acceptor PropertiesNatural SciencesCoordination ComplexSpectra-structure CorrelationAbsorption SpectroscopyPhysical ChemistryMolecular ComplexComputational ChemistryQuantum ChemistryChemistryBiophysicsLigand Field Spectra
Abstract The influence of solvents on the electronic absorption spectra of chromium (III) complexes was investigated. The dependence of the crystal field parameter Dq on dielectric constant as well as Gutmann donor number DN of solvent was found and described. By using the proposed model, unknown in the literature donor numbers for a few alcohols were estimated.
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