Journal of the American Chemical Society · 2011 · 135 citations · 55 references
Natural SciencesChemistryCatalysisOrganic ChemistryCatalyst DesignCatalyst PreparationCatalyst SynthesisCatalytic MechanismsCross-coupling ReactionsSupported CatalystsAsymmetric CatalysisAsymmetric Catalyst DesignAsymmetric Cross-couplingCatalyst Structure - Activity RelationshipsChiral Carboxylic AcidsEnantioselective CatalysisEnantioselective Cross-couplingEnantioselective Synthesis
We report on the first intermolecular asymmetric catalytic regio- and enantioselective addition of carboxylic acids to terminal allenes to form valuable branched allylic esters, employing a rhodium(I)/(R,R)-DIOP catalyst system.
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