Palladium‐Indium‐Indium(III) Chloride‐Mediated Allyl Cross‐Coupling Reactions Using Allyl Acetates

Phil Ho Lee, Dong Seomoon, Kooyeon Lee, Sundae Kim, Hyunseok Kim, Tae Hyun Kim, Eunkyong Shim, Mi-Ae Lee, Seokju Lee, Misook Kim,

Advanced Synthesis & Catalysis · 2004 · 34 citations · 58 references

Concepts

Abstract

Abstract Allylindiums in situ generated by reductive transmetalation of π‐allylpalladium(II) complexes, obtained from allyl acetates and palladium(0) catalyst, with indium and indium(III) chloride are effective nucleophilic cross‐coupling partners in Pd‐catalyzed allyl cross‐coupling reactions with a variety of electrophilic cross‐coupling partners.

References

58