Concepedia

Cyclopalladated complexes in enantioselective catalysis

Olga N. Gorunova, P. A. Zykov

Russian Chemical Reviews · 2011 · 49 citations · 26 references

DOI

Concepts

Abstract

The results of the use of optically active palladacycles in enantioselective catalysis of [3,3]-sigmatropic rearrangements, aldol condensation, the Michael reaction and cross-coupling are analyzed. Reactions with allylic substrates or reagents and some other transformations are considered.

References

26

Oxazoline‐Mediated Interannular Cyclopalladation of Ferrocene: Chiral Palladium(<scp>II</scp>) Catalysts for the Enantioselective Aza‐Claisen Rearrangement

Albert Moyano, Malgorzata Rosol, Rosa M. Moreno et al. · Angewandte Chemie International Edition · 2005 · 145 citations · Full text

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Practical, Highly Active, and Enantioselective Ferrocenyl–Imidazoline Palladacycle Catalysts (FIPs) for the Aza‐Claisen Rearrangement of <i>N</i>‐<i>para</i>‐Methoxyphenyl Trifluoroacetimidates

Matthias E. Weiss, Daniel F. Fischer, Zhuo‐Qun Xin et al. · Angewandte Chemie International Edition · 2006 · 136 citations

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The Asymmetric Aza‐Claisen Rearrangement: Development of Widely Applicable Pentaphenylferrocenyl Palladacycle Catalysts

Daniel F. Fischer, Assem Barakat, Zhuo‐qun Xin et al. · Chemistry - A European Journal · 2009 · 117 citations

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Asymmetric Formation of Allylic Amines with N‐Substituted Quaternary Stereocenters by Pd<sup>II</sup>‐Catalyzed Aza‐Claisen Rearrangements

Daniel F. Fischer, Zhuo‐qun Xin, René Peters · Angewandte Chemie International Edition · 2007 · 113 citations

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Macrocyclic Ferrocenyl–Bisimidazoline Palladacycle Dimers as Highly Active and Enantioselective Catalysts for the Aza‐Claisen Rearrangement of <i>Z</i>‐Configured <i>N</i>‐<i>para</i>‐Methoxyphenyl Trifluoroacetimidates

Sascha Jautze, Paul Seiler, René Peters · Angewandte Chemie International Edition · 2007 · 111 citations

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