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C(sp)–C(sp<sup>3</sup>) Bond Formation through Cu-Catalyzed Cross-Coupling of <i>N</i>-Tosylhydrazones and Trialkylsilylethynes
185
Citations
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References
2012
Year
Inorganic ChemistryCross-coupling ReactionKey RoleEngineeringTrialkylsilylethynes LeadsOrganic ChemistryOrganometallic CatalysisCatalysisChemistryBond FormationAsymmetric CatalysisCopper-catalyzed Cross-couplingBiomolecular Engineering
Copper-catalyzed cross-coupling of N-tosylhydrazones with trialkylsilylethynes leads to the formation of C(sp)-C(sp(3)) bonds. Cu carbene migratory insertion is proposed to play the key role in this transformation.
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