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A chiral Rh–phosphite complex displaying high activity in the enantioselective Rh-catalyzed addition of arylboronic acids to carbonyl compounds: when and why atropos is better than tropos

Arylboronic AcidsEngineeringOrganic ChemistryCatalysisChemistryChiral Rh–phosphite ComplexAsymmetric CatalysisSynthetic ChemistryEnantioselective SynthesisBiomolecular EngineeringHigh Activity