Concepedia

A new type of alumoxane obtained by controlled hydrolysis of N,N-dialkylcarbamato complexes of aluminium; crystal and molecular structure of [Al4(µ3-O)2(O2CNPri2)8]

Ulrich Abram, Stefan Kaskel, Joachim Strähle, Daniela Belli Dell’Amico, Fausto Calderazzo, Luca Labella, Fabio Marchetti, Riccardo Rovai

Chemical Communications · 1997 · 27 citations · 19 references

DOI

Concepts

Abstract

The aluminium(III) N,N-diisopropylcarbamato derivative [Al2(O2CNPri2)6] undergoes hydrolysis with a stoichiometric amount of water giving the µ3-oxo derivative [Al4(µ3-O)2(O2CNPri2)8], which is analytically, spectroscopically and structurally characterized.

References

19

Hydrolysis of tri-tert-butylaluminum: the first structural characterization of alkylalumoxanes [(R2Al)2O]n and (RAlO)n

Mark R. Mason, J. M. Smith, Simon G. Bott et al. · Journal of the American Chemical Society · 1993 · 547 citations

, , +6

Tert-Butylaluminum Hydroxides and Oxides: Structural Relationship between Alkylalumoxanes and Alumina Gels

C. Jeff Harlan, Mark R. Mason, Andrew R. Barron · Organometallics · 1994 · 217 citations

, , +9

Crystal-Molecular Structure and Magnetic Properties of Cr3 (CH3.COO)6 O Cl.5H2O

B. N. Figgis, G. B. Robertson · Nature · 1965 · 191 citations

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Vibrational spectra of carboxylato complexes—III. Trinuclear ‘basic’ acetates and formates of chromium(III), iron(III) and other transition metals

M.K. Johnson, D.B. Powell, Richard D. Cannon · Spectrochimica Acta Part A Molecular Spectroscopy · 1981 · 160 citations

, , +16

<sup>27</sup>AI‐NMR Spectroscopy: A Probe for Three‐, Four‐, Five‐, and Sixfold Coordinated Al Atoms in Organoaluminum Compounds

Reinhard Benn, Anna Rufińska, Herbert Lehmkuhl et al. · Angewandte Chemie International Edition in English · 1983 · 154 citations

, , +11