Journal of the Chemical Society Dalton Transactions · 1972 · 14 citations · 0 references
Natural SciencesChemistryCrystal StructureInorganic ChemistryPhysical ChemistryCoordination ChemistryCrystal ChemistryCrystal Field TheoryCrystal SymmetryMagnetic Properties Of SolidsMagnetism In SolidsCoordination Compound MagnetismCrystal Field AnalysisCrystal Field Effects In Solid-state MaterialsCrystal Field ParametersCrystal-field EffectsElectronic Structure Of Metal ComplexesMagnetic Properties Of Transition Metal ComplexesMetal-ligand Bonding In Crystal Fields
The single-crystal polarised electronic spectra, e.s.r., and magnetic anisotropy of tetra-(6-aminohexanoic acid)copper(II) diperchlorate are reported. These properties are interpreted by use of a point-charge crystal-field model and are seen to be consistent with the relative orbital energies, dxy > dx2–y2 > dz2 > dxz yz. The crystal-field parameters obtained are shown to agree closely with those for CaCu(AcO)4,6H2O when allowance is made for the different Cu–O distances involved.