Oxygen-vacancy-related high-temperature dielectric relaxation in SrTiO3 ceramics

Abstract

Quantum paraelectric SrTiO3 has resulted in many investigations because of the anomalous properties. Here, using the conventional solid-state reaction method, we fabricated polycrystalline SrTiO3 ceramics with pure cubic perovskite structure. A dielectric loss peak is observed at around 450 K and 100 Hz and it shifts to higher temperature with increasing frequency. The typical high-temperature dielectric relaxation process is confirmed to be related to the oxygen vacancies (OVs) inside ceramics. More interestingly, a Cole–Cole fitting to loss peaks reveals a weaker correlation among OVs for such dielectric materials compared with that of ferroelectrics.