Concepedia

Synthesis of Constrained-Geometry Chiral Di-N-Heterocyclic Carbene Ligands and Their Silver(I) and Palladium(II) Complexes

L.G. Bonnet, Richard E. Douthwaite, Richard Hodgson

Organometallics · 2003 · 120 citations · 32 references

DOI

Concepts

Abstract

Silver(I) and palladium(II) complexes of constrained-geometry chiral di-N-heterocyclic carbenes have been prepared from trans -1,2-diaminocyclohexane via the base-induced 1,3-cycloaddition of tosylmethyl isocyanide to diimines.

References

32

Synthesis and Activity of a New Generation of Ruthenium-Based Olefin Metathesis Catalysts Coordinated with 1,3-Dimesityl-4,5-dihydroimidazol-2-ylidene Ligands

Matthias Scholl, Sheng Ding, Choon Woo Lee et al. · Organic Letters · 1999 · 3.4K citations

, , +15

Asymmetric Catalysis by Architectural and Functional Molecular Engineering: Practical Chemo- and Stereoselective Hydrogenation of Ketones

Ryōji Noyori, Takeshi Ohkuma · Angewandte Chemie International Edition · 2001 · 1.9K citations · Full text

, , +15

Asymmetric Catalysis with Water: Efficient Kinetic Resolution of Terminal Epoxides by Means of Catalytic Hydrolysis

Makoto Tokunaga, Jay F. Larrow, Fumitoshi Kakiuchi et al. · Science · 1997 · 1.4K citations

, , +17

The development of versions 3 and 4 of the Cambridge Structural Database System

Frank H. Allen, John E. Davies, J. Galloy et al. · Journal of Chemical Information and Computer Sciences · 1991 · 1.3K citations

, , +11

Facile Synthesis of Silver(I)−Carbene Complexes. Useful Carbene Transfer Agents

Harrison M. J. Wang, Ivan J. B. Lin · Organometallics · 1998 · 1.2K citations

, , +17