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Mechanism of Alloy Corrosion and Consequences on Sealed Nickel—Metal Hydride Battery Performance
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1998
Year
EngineeringChemical EngineeringCorrosionCorrosion RateAb5 AlloyBattery DegradationCorrosion ResistanceMaterials ScienceAlloy CorrosionBattery Electrode MaterialsMechanical BatteriesEnergy StorageHydrogenElectrochemistryElectric BatteryCorrosion TechnologyLi-ion Battery MaterialsMetal AnodeHydrogen Storage AlloyElectrochemical Energy StorageBatteries
The degradation mechanism of hydrogen storage alloy in nickel‐metal hydride (Ni‐MH) sealed batteries and effects of corrosion on cell performance during cycling are investigated. A general equation for the corrosion of AB5 alloy is derived from analyses of corrosion products in cycled electrodes and measurements of negative discharge reserve. Water consumption due to alloy corrosion explains the increase of impedance during cycling while internal pressure evolution is directly linked to the loss of charge reserve. The parameters controlling the corrosion rate of AB5 alloys are also examined. It is shown that the pulverization mode of the alloy particles rather than the surface reactivity to electrolyte explains the differences in cycle‐life performance of alloys of various compositions.