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Derivatives of cis-NPCl<sub>2</sub>(NSOCl)<sub>2</sub> and (NPCl<sub>2</sub>)<sub>2</sub>NSOCl, Part X [1] Aminolysis of cis-NPCl<sub>2</sub>(NSOF)<sub>2</sub> and (NPCl<sub>2</sub>)<sub>2</sub>NSOF
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1978
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Derivative (Chemistry)DerivativesEngineeringBiochemistryHeterocyclicNatural SciencesChemical BondChemical DerivativePart XMolecular BiologyStructure ElucidationOrganic ChemistryAmino DerivativesChemistryHeterocycle ChemistryNpcl 2Biomolecular EngineeringSystems Cis-npcl 2
The aminolysis of the ring systems cis-NPCl 2 (NSOF) 2 and (NPCl 2 ) 2 NSOF by cyclic amines in acetonitrile at room temperature shows the S-F bond to be stable towards a nucleophilic attack. The amino derivatives are characterized by their spectral data. Structure assignments are based on 31 P NMR spectroscopy.