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An Oxygen‐Deficient Perovskite as Selective Catalyst in the Oxidation of Alkyl Benzenes
58
Citations
16
References
2011
Year
EngineeringExtraordinary Reaction RatesOxygen-deficient CatalystHalide PerovskitesOrganic ChemistryHeterogeneous Perovskite CatalystChemistryPerovskite ModuleAlkyl BenzenesHomogeneous CatalysisMaterials ScienceInorganic ChemistryPerovskite MaterialsCatalysisLead-free PerovskitesCatalytic SynthesisSelective CatalystOxygen Reduction ReactionPerovskite Solar CellOxygen‐deficient Perovskite
Extraordinary reaction rates and selectivity for the conversion of alkyl aromatic compounds, such as p-xylene, in terephthalic acid were observed for a heterogeneous perovskite catalyst of composition (La,Sr)0.5(Mn,Co)0.5O2.38 (see picture). The oxygen-deficient catalyst was prepared by reduction of the oxygen-stoichiometric parent compound.
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