Molecular Weights of Cyclic and Hollow Clusters Measured by DOSY NMR Spectroscopy

Abstract

The Stokes-Einstein expression of the diffusion coefficient as a function of the hydrodynamic radius of the diffusing object does not explicitly carry the mass dependency of the object. It is possible to correlate the translational self-diffusion coefficients D with the molecular weight M for an ensemble of cyclic or hollow clusters ranging from about 200 to 30,000 g x mol(-1). From this correlation, the mass of a cluster can be deduced from its diffusion coefficient. Consistency of diffusion as a power law of mass and Stokes-Einstein formulation is completely fulfilled with the selected compounds of this contribution.