Synthetic Communications · 1987 · 13 citations · 4 references
Natural SciencesChemistryMedicinal ChemistryOrganic ChemistrySteroid BiochemistryHeterocycle SynthesisHeterocyclic ChemistryHeterocyclic CompoundsPhotochemical SynthesisPhotochemistrySteroid StructureFive-membered HeterocyclesHeterocyclic AromaticityHeterocyclic ReactivityHeterocyclic Ring OpeningPhotochemical CycloadditionPhotochemical ReactivityPhotocyclization ReactionsPolycyclic Heterocycles
Abstract The bicyclo [5.3.1] undecane derivative 12, an important structural element of the taxane diterpenes, was prepared by photocycloaddition of the bicyclo [3.3.1] dione 9 to allene followed by cyclobutane ring opening (the de Mayo reaction).
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Model studies in the taxane diterpene series - Part. I
Humberto Cervantes, Duc Do Khac, M. FETIZON et al. · Tetrahedron · 1986 · 15 citations