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Regio- and stereo-selective γ-substitution of allylic sulphoxides and sulphones with lithium dialkylcuprates. A new synthesis of trisubstituted olefins
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1980
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EngineeringLithium DialkylcupratesStereo-selective γ-SubstitutionTrisubstituted OlefinsOrganic ChemistryStereoselective SynthesisChemistrySynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
A new regio- and stereo-selective γ-substitution of allylic sulphoxides and sulphones with lithium dialkylcuprates providing a promising new method for the preparation of trisubstituted olefins in particular is described.