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P…N Interaction and its Effect on the Structure and Properties of Phosphorylated α-Aminoketones Derivatives
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1993
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Medicinal ChemistryPhosphorylated α-Aminoketones DerivativesDerivative (Chemistry)BiochemistryNatural SciencesMolecular BiologyP…n InteractionProtein PhosphorylationOrganic ChemistryAbstract ReactionsSynthetic ChemistryChemistryCationes XvChemical BiologyChemical DerivativeBasic MediumEnantioselective Synthesis
Abstract Reactions of α-aminoketones with P-chlorides in a basic medium are reported. Methods for the synthesis of Δ4-1,3,2-oxazahospholines and ß-amino of phosphorus from N to O and enamin-imine isomerization are discussed for the phosphorylated aminoketones. Nucleophylic and electrophylic reactivity of cationes XV and XVI was studied.