Angewandte Chemie International Edition · 2014 · 65 citations · 33 references
Natural SciencesChemistryMaterials ScienceCrystal StructureMaterials ChemistrySolid-state ChemistryCluster ChemistryCrystal EngineeringNanoporous MaterialsPorous MaterialsCoordination PolyhedraMesoporosity EngineeringMesoporous MaterialsMetal-organic Framework SynthesisMetal-organic FrameworksPore Architecture
A new porous vanadoborate was synthesized by employing the scale chemistry theory with the vanadoborate cluster V10B28. The twofold interpenetrated lvt network was assembled with zinc-containing elliptical vanadoborate clusters and Zn polyhedra. The single lvt framework contains a three-dimensional 38×38×20 ring channel system with the pore size (24.7×12.7 Å) reaching the mesoscale, thus indicating the possibility of constructing 3D ordered mesopores with vanadoborate clusters. The porosity of the SUT-7 structure was confirmed by CO2 adsorption of the as-synthesized materials.
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A short history of<i>SHELX</i>
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Large-Pore Apertures in a Series of Metal-Organic Frameworks
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