Publication | Closed Access
Hydrogen abstraction reactions by atomic fluorine. III. Temperature dependence of the intermolecular kinetic isotope effect for the thermal F+H2 reaction
32
Citations
55
References
1975
Year
EngineeringNuclear PhysicsNuclear DataTemperature DependenceChemistryTitle ReactionNuclear MaterialsAtomic FluorineRadiation ChemistryNuclear ReactorsQuantitative AgreementNuclear DynamicsHigh-energy Nuclear ReactionPhysicsPhysical ChemistryNuclear ReactionsHydrogen Abstraction ReactionsHydrogenQuantum ChemistryNuclear EngineeringExperimental Nuclear PhysicsNuclear Recoil ProcedureHydrogen TransitionNatural SciencesHydrogen BondRadioanalytical ChemistryChemical Kinetics
The intermolecular kinetic isotope effect for the title reaction has been investigated using a moderated nuclear recoil technique. The following Arrhenius temperature dependence was obtained: kH2/kD2 = (1.04±0.06)exp[(382±35)/RT]. This result is in quantitative agreement with an independent study based upon a discharge flow reactor method. The advantages and limitations of the nuclear recoil procedure are considered, and relevant literature results are critically reviewed.
| Year | Citations | |
|---|---|---|
Page 1
Page 1