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Rearrangement of prop-2-ynylic N-oxides to O-allenyl hydroxylamines
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1979
Year
EngineeringBiochemistryIntramolecular ProceedingCyclic MechanismNatural SciencesN-prop-2-ynylpiperidine N-oxideOrganic ChemistryO-allenyl HydroxylaminesCatalysisStereoselective SynthesisChemistrySynthetic ChemistryEnantioselective SynthesisBiomolecular Engineering
Rearrangement of N-prop-2-ynylpiperidine N-oxide and N-prop-2-ynylmorpholine N-oxide to the corresponding O-allenyl hydroxylamines is reported; this rearrangement appears to be intramolecular proceeding by a cyclic mechanism.