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An attempted synthesis of an oxacepham derivative using isonitriles as β-lactam forming agents. On the stability of dihydrooxazines and the inadequacy of ammonia as the fourth component in the Ugi reaction
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1977
Year
EngineeringAttempted SynthesisBiochemistryNatural SciencesUgi ReactionFourth Componentβ-Lactam Forming AgentsOrganic ChemistryOxacepham DerivativeStereoselective SynthesisChemistryPharmacologyChemical DerivativeSynthetic ChemistryEnantioselective SynthesisBiomolecular EngineeringNatural Product Synthesis
An attempted synthesis of an oxacepham derivative, using isonitriles as β-lactam forming agents, is described. The reasons for the failure of this approach are discussed.