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A New Synthesis of Alkyl-N,N-dinitramines by Direct Nitration of Isocyanates
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1991
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Direct NitrationAliphatic IsocyanateHeterocyclicNitric AcidAliphatic IsocyanatesOrganic ChemistryChemistryHeterocycle ChemistryPharmacologySynthetic ChemistryNatural Product Synthesis
Abstract A facile conversion of aliphatic isocyanates to N,N-dinitramines has been developed. An aliphatic isocyanate is treated with a mixture of nitronium fluoroborate and nitric acid in acetonitrile giving fair yields and simplifing the existing synthesis.