Effect of crystallinity on the electrochemical properties of carbon black electrodes

Abstract

Carbon-based electric double-layer capacitors are being evaluated as potential energy-storage devices in an expanding number of applications. In this study, samples of carbon black (CB) treated at different temperatures ranging from <TEX>$650^{\circ}C$</TEX> to <TEX>$1100^{\circ}C$</TEX> were used as electrodes to improve the efficiency of a capacitor. The surface properties of the heat-treated CB samples were characterized by X-ray photoelectron spectroscopy and X-ray diffraction. The effect of the heat-treatment temperature on the electrochemical behaviors was investigated by cyclic voltammetry and in galvanostatic charge-discharge experiments. The experimental results showed that the crystallinity of the CBs increased as the heat-treatment temperature increased. In addition, the specific capacitance of the CBs was found to increase with the increase in the heat-treatment temperature. The maximum specific capacitance was 165 <TEX>$F{\cdot}g-1$</TEX> for the CB sample treated at <TEX>$1000^{\circ}C$</TEX>.