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Formation of β-lactams from tricarbonyliron lactone complexes
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1980
Year
Inorganic ChemistryEngineeringTricarbonyliron Lactone ComplexesBiochemistryExcellent YieldNatural SciencesCoordination ComplexOrganic ChemistryOrganometallic CatalysisChemistrySynthetic ChemistryInorganic SynthesisTricarbonyliron Lactam ComplexesLactone Complexes
A number of tricarbonyliron lactam complexes were prepared from the corresponding lactone complexes by reaction with amines in the presence of ZnCl2 and on subsequent oxidation with CeIV gave β-lactams in excellent yield.