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Experimental Evidence of a Ferromagnetic Ground State (<i>S</i> = <sup>9</sup>/<sub>2</sub>) for a Dinuclear Gd(III)−Ni(II) Complex
176
Citations
9
References
1997
Year
Magnetic PropertiesDinuclear GdEngineeringMagnetic ResonanceChemistryFerromagnetic Ground StateMagnetic MaterialsInorganic CompoundMagnetismQuantum MaterialsEnvironmental MagnetismInorganic ChemistryPhysicsStrict DinuclearityNickel IonCrystallographyQuantum MagnetismExperimental EvidenceNatural SciencesCondensed Matter PhysicsApplied Physics
The structural determination of a dinuclear Gd(III)−Ni(II) entity confirms the strict dinuclearity of the complex while the magnetic properties evidence the presence of a ferromagnetic interaction between the paramagnetic (S = 1) nickel ion and the gadolinium center (S = 7/2), with a J value of 3.6 cm-1.
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