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A novel and stereospecific synthesis of conduritol-A
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1988
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EngineeringStereospecific SynthesisHydroxy GroupsNatural SciencesDiversity-oriented SynthesisOrganic ChemistryStereoselective SynthesisChemistryHeterocycle ChemistryPharmacologySynthetic ChemistryClassical Kmno4-oxidationBiomolecular EngineeringDesired Conduritol-aNatural Product Synthesis
A new and stereospecific synthesis for conduritol-A has been developed starting from cyclohexa-1,4-diene where hydroxy groups have been introduced by classical KMnO4-oxidation followed by photo-oxygenation; suitable ring-opening reactions gave the desired conduritol-A.