Journal of the American Chemical Society · 2013 · 143 citations · 23 references
Natural SciencesChemistryMaterials ScienceCatalysisMaterials ChemistrySolid-state ChemistryPorous MaterialsSolid-gas InterfacesSulfur ChemistrySulfur DioxideSulfur Dioxide StabilitySulfur OxidesSulfur Dioxide ChemistrySulfur Dioxide OxidationSulfur Dioxide Uptake KineticsTemperature Effects On Sulfur Dioxide Stability
Porous NOTT-202a shows exceptionally high uptake of SO2, 13.6 mmol g(-1) (87.0 wt %) at 268 K and 1.0 bar, representing the highest value reported to date for a framework material. NOTT-202a undergoes a distinct irreversible framework phase transition upon SO2 uptake at 268-283 K to give NOTT-202b which has enhanced stability due to the formation of strong π···π interactions between interpenetrated networks.
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Shape-Memory Nanopores Induced in Coordination Frameworks by Crystal Downsizing
Yoko Sakata, Shuhei Furukawa, Mio Kondo et al. · Science · 2013 · 581 citations