Concepedia

Long‐Range Electronic Coupling in Various Oxidation States of a C<sub>4</sub>‐Linked Tris(β‐diketonato)ruthenium Dimer

Yoshimasa Hoshino, Seiichiro HIGUCHI, Jan Fiedler, Cheng‐Yong Su, Axel Knödler, Brigitte Schwederski, Biprajit Sarkar, Heiko Hartmann, Wolfgang Kaim

Angewandte Chemie International Edition · 2003 · 50 citations · 15 references

DOI

Concepts

Abstract

Getting the message across: Strong electronic coupling over a distance of 1.3 nm is observed for the Ru state of the complex 1n (n=+). The fully delocalized system 1+ is distinguished by an extremely intense intervalence charge-transfer (IVCT) band and a single intense vibrational band.

References

15

Elemental Carbon Chain Bridging Two Iron Centers: Syntheses and Spectroscopic Properties of [Cp*(dppe)Fe-C4-FeCp*(dppe)]n+.cntdot.n[PF6]-. X-ray Crystal Structure of the Mixed Valence Complex (n = 1)

Nathalie Le Narvor, Claude Lapinte · Journal of the American Chemical Society · 1995 · 434 citations

, , +15

Consanguineous Families of Coordinated Carbon:  A ReC<sub>4</sub>Re Assembly That Is Isolable in Three Oxidation States, Including Crystallographically Characterized ReC⋮CC⋮CRe and<sup>+</sup>ReCCCCRe<sup>+</sup>Adducts and a Radical Cation in Which Charge Is Delocalized between Rhenium Termini

Monika Brady, Weiqing Weng, Yuanlin Zhou et al. · Journal of the American Chemical Society · 1997 · 286 citations

, , +16

Oxidation Chemistry of Metal-Bonded C<sub>4</sub>Chains:  A Combined Chemical, Spectroelectrochemical, and Computational Study

Michael I. Bruce, Paul J. Low, Karine Costuas et al. · Journal of the American Chemical Society · 2000 · 279 citations

, , +15

The coordination chemistry of 1,2,4,5-tetrazines

Wolfgang Kaim · Coordination Chemistry Reviews · 2002 · 279 citations

, , +1

When Is an Odd-Electron Dinuclear Complex a Mixed-Valent Species? Tuning of Ligand-to-Metal Spin Shifts in Diruthenium(III,II) Complexes of Noninnocent Bridging Ligands OC(R)NNC(R)O

Volker Kasack, Wolfgang Kaim, H. Binder et al. · Inorganic Chemistry · 1995 · 156 citations

, , +14