Concepedia

Ruthenium-catalysed disproportionation between vinylsilanes and mono-substituted alkenes via silyl group transfer

Yasuo Wakatsuki, Hiroshi Yamazaki, Masato Nakano, Yasuhiro Yamamoto

Journal of the Chemical Society Chemical Communications · 1991 · 123 citations · 6 references

DOI

Concepts

Abstract

Selective cross-disproportion between vinylsilanes and various mono-substituted alkenes is catalysed by [RuCl(CO)H(PPh3)3]1; the mechanism of this reaction has been elucidated based on reactions of 1 with vinylsilanes as well as those of the resulting ruthenium–silyl complex with alkenes.

References

6

Photochemical reactions of (.eta.5-pentamethylcyclopentadienyl)dicarbonyliron alkyl and silyl complexes: reversible ethylene insertion into an iron-silicon bond and implications for the mechanism of transition-metal-catalyzed hydrosilation of alkenes

C. L. RANDOLPH, Mark S. Wrighton · Journal of the American Chemical Society · 1986 · 160 citations

, , +13

Single-operation synthesis of vinylsilanes from alkenes and hydrosilanes with the aid of Ru3(CO)12

Yoshio Seki, Kenji Takeshita, Kazuaki Kawamoto et al. · The Journal of Organic Chemistry · 1986 · 82 citations

, , +17

The catalyzed reaction of .alpha.,.beta.-unsaturated esters with various hydrosilanes

Kenji Takeshita, Yoshio Seki, Kazuaki Kawamoto et al. · The Journal of Organic Chemistry · 1987 · 80 citations

, , +9

The synthesis of (E)-1,2-disilylethenes from a triorganosilylethene with the aid of Ru3(CO)12 and a hydrosilane

Yoshio Seki, Kenji Takeshita, Kazuaki Kawamoto · Journal of Organometallic Chemistry · 1989 · 43 citations

, , +4

Metathesis of silicon containing olefins: II. Synthesis of 1,2-bis(silyl)ethenes by metathesis of vinylsilanes☆

Bogdan Marciniec, Hieronim Maciejewski, Jacek Guliński et al. · Journal of Organometallic Chemistry · 1989 · 41 citations