Concepedia

Longstanding living polymerization of ethylene: substituent effect on bridging carbon of 2-pyridinemethanamine nickel catalysts

Shaobo Zai, Feng‐Shou Liu, Haiyang Gao, Cong Li, Guiyu Zhou, Shan Cheng, Lihua Guo, Ling Zhang, Fangming Zhu, Qing Wu

Chemical Communications · 2010 · 65 citations · 31 references

DOI

Concepts

Abstract

Bulky 2-pyridinemethanamine nickel complex activated by MAO was used as a catalyst to conduct longstanding living ethylene polymerization under atmospheric pressure to produce branched polyethylene.

References

31

New Pd(II)- and Ni(II)-Based Catalysts for Polymerization of Ethylene and .alpha.-Olefins

Lynda K. Johnson, Christopher M. Killian, Maurice Brookhart · Journal of the American Chemical Society · 1995 · 2.7K citations

, , +14

Synthesis of Branched Polyethylene Using (α-Diimine)nickel(II) Catalysts:  Influence of Temperature, Ethylene Pressure, and Ligand Structure on Polymer Properties

Derek P. Gates, Steven A. Svejda, Enrique Oñate et al. · Macromolecules · 2000 · 717 citations

, , +17

Living alkene polymerization: New methods for the precision synthesis of polyolefins

Gregory J. Domski, Jeffrey M. Rose, Geoffrey W. Coates et al. · Progress in Polymer Science · 2007 · 657 citations

, , +15

Catalysts for the Living Insertion Polymerization of Alkenes: Access to New Polyolefin Architectures Using Ziegler–Natta Chemistry

Geoffrey W. Coates, Phillip D. Hustad, Stefan Reinartz · Angewandte Chemie International Edition · 2002 · 616 citations

, , +17

Mechanistic Studies of Pd(II)−α-Diimine-Catalyzed Olefin Polymerizations<sup>1</sup>

Daniel J. Tempel, Lynda K. Johnson, R. Leigh Huff et al. · Journal of the American Chemical Society · 2000 · 601 citations

, , +16