Concepedia

Minor changes in phosphonate ligands lead to new hexa- and dodeca-nuclear Mn clusters

Maheswaran Shanmugam, Muralidharan Shanmugam, Guillaume Chastanet, Roberta Sessoli, Talal Mallah, Wolfgang Wernsdorfer, Richard E. P. Winpenny

Journal of Materials Chemistry · 2006 · 47 citations · 9 references

DOIFull text

Open access

Concepts

Abstract

Drastic changes in the structure of manganese clusters are observed from a minor modification of a phosphonate ligand.

References

9

Magnetic bistability in a metal-ion cluster

Roberta Sessoli, Dante Gatteschi, Andréa Caneschi et al. · Nature · 1993 · 4.3K citations

, , +14

Quantum Tunneling of Magnetization and Related Phenomena in Molecular Materials

Dante Gatteschi, Roberta Sessoli · Angewandte Chemie International Edition · 2003 · 2.8K citations

, , +15

Macroscopic quantum tunnelling of magnetization in a single crystal of nanomagnets

F. Lionti, R. Ballou, Dante Gatteschi et al. · Nature · 1996 · 2K citations

, , +14

Exchange-biased quantum tunnelling in a supramolecular dimer of single-molecule magnets

Wolfgang Wernsdorfer, Núria Aliaga‐Alcalde, David N. Hendrickson et al. · Nature · 2002 · 962 citations

, , +16

Preparation and physical properties of trinuclear oxo-centered manganese complexes of general formulation [Mn3O(O2CR)6L3]0,+ (R = methyl or phenyl; L = a neutral donor group) and the crystal structures of [Mn3O(O2CMe)6(pyr)3](pyr) and [Mn3O(O2CPh)6(pyr)2(H2O)].cntdot.0.5MeCN

John B. Vincent, H.‐R. CHANG, Kirsten Folting et al. · Journal of the American Chemical Society · 1987 · 310 citations

, , +15