Science · 1966 · 11 citations · 2 references
Natural SciencesChemistryInorganic ChemistryPhase TransformationsHigh-pressure ThermodynamicsHydrate FormationHydrationHydration EffectsPhase Changes Of WaterDehydration ReactionsHydrate Formation KineticsHydrate KineticsHydrate ThermodynamicsPressure Effects On Hydrate FormationPressure-dependent ReactionsReversible Phase TransformationsTemperature Effects On Hydrate Formation
Application of high pres sure at 250 degrees C irreversibly dehydrated five inorganic compounds containing molecular water to lower hydrates or to anhydrous forms. Compression at 250 degrees C also lead to ten new reversible phase transformations in another group of nine hydrates. Maximum pressure applied was 22.6 kilobars.
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