A promising new route towards single-molecule magnets based on the oxalate ligand

Gong‐Feng Xu, Qing‐Lun Wang, Patrick Gámez, Yue Ma, Rodolphe Clérac, Jinkui Tang, Shi‐Ping Yan, Peng Cheng, Dai‐Zheng Liao

Chemical Communications · 2009 · 240 citations · 36 references

Concepts

Abstract

A unique purely lanthanide-based single-molecule magnet (SMM) with an oxalate bridge has been designed through a rational synthetic approach. This strategy opens up new opportunities to design SMMs through the premeditated choice of a blocking ligand and suitable oxalate bridge.

References

36