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Branched-chain sugars in asymmetric synthesis. Total synthesis of marine antibiotic (−)-malyngolide
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1985
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Bioorganic ChemistryEngineeringBranched-chain SugarsOrganic ChemistryMedicinal ChemistryBiosynthesisDiversity Oriented SynthesisStereoselective SynthesisBiochemistryDiversity-oriented SynthesisAsymmetric SynthesisTotal SynthesisPharmacologyAsymmetric CatalysisNatural Product SynthesisEnantioselective SynthesisBiomolecular EngineeringNatural SciencesSynthetic Chemistry
Marine antibiotic (−)-malyngolide has been stereospecifically synthesized in about 25% overall yield from 2,3-O-isopropyl-idene-D-apiose, easily prepared from D-mannose.